Pressureless all‐solid‐state Na/S batteries with self‐supporting Na<sub>5</sub>YSi<sub>4</sub>O<sub>12</sub> scaffolds

نویسندگان

چکیده

The development of reliable and affordable all-solid-state sodium metal batteries (ASS-SMBs) requires suitable solid-state electrolytes with cost-efficient processing stabilized electrode/electrolyte interfaces. Here, an integrated porous/dense/porous Na5YSi4O12 (NYS) trilayered scaffold is designed fabricated by tape casting using aqueous slurries. In this template-based NYS scaffold, the dense layer in middle serves as a separator porous layers on both sides accommodate active materials their volume changes during charge/discharge processes, increasing contact area thus enhancing utilization rate homogenizing current distribution. Na/NYS/Na symmetric cells Pb-coated exhibit significantly reduced interfacial impedance superior critical density up to 3.0 mA cm−2 against Na owing enhanced wettability. Furthermore, assembled Na/NYS/S full operated without external pressure at room temperature showed high initial discharge capacity 970 mAh g−1 good cycling stability 600 after 150 cycles (based mass sulfur). This approach paves way for realization economical practical ASS-SMBs from perspective ceramic manufacturing.

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ژورنال

عنوان ژورنال: Carbon energy

سال: 2023

ISSN: ['2096-9570', '2637-9368']

DOI: https://doi.org/10.1002/cey2.371